Product ID:08605GUZ-GD 383 GREEN ZENTHANE, MIL-C-53039A
MSDS Date:08/31/1995
FSC:8010
NIIN:01-229-9561
MSDS Number: CBTWB

HENTZEN COATINGS INC

6937 W MILL ROAD
MILWAUKEE, WI 53218-1225
US

Emergency Phone: 414-353-4200

Info Phone: 414-353-4200 / FAX 414-353-0286

Preparer: JANE FREEMAN

Cage: 09225

HENTZEN COATINGS INC

18749 MILWAUKEE, WI 53218 US

Telephone: 414-353-4200

Cage: 09225

METHYL ISOAMYL KETONE SOLVENT

CAS: 110-12-3

RTECS: MP3850000

Fraction By Weight: 20.516%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

SILICA PIGMENT (SARA 313)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 20-30%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3

HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE (HDI)(EXACT

CAS: 28182-81-2

RTECS: HQ9170000

Fraction By Weight: 20-30%

AROMATIC HYDROCARBONS (MIXTURE OF C8'S TO C10'S)

CAS: 64742-95-6

Fraction By Weight: 1.497%

BUTYL ACETATE SOLVENT

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 1.194%

OSHA PEL 150 PPM/STEL 200 PPM

ACGIH TLV: 150 PPM/STEL 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HEXAMETHYLENE DIISOCYANATE MONOMER (SARA 313)

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: 0.047%

OSHA PEL 0.005 PPM

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

VM&P NAPHTHA SOLVENT

CAS: 8030-30-6

RTECS: DE3030000

Fraction By Weight: 4.795%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

XYLENE (SARA 313)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 4.875%

OSHA PEL 100 PPM/STEL 150 PPM

ACGIH TLV: 100 PPM/STEL 150 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

3.497 LBS/GAL; 419.045 GRAMS/LITER

RTECS: 9999999VO

MAGNESIUM FERRITE PIGMENT

CAS: 12068-86-9

Fraction By Weight: 1-5%

OSHA PEL 10 MG/M3

ACGIH TLV: 15 MG/M3

COBALT COMPOUNDS (AS CO)(SARA 313)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: 0.429%

OSHA PEL 0.05 MG/M3

ACGIH TLV: 0.05 MG/M3

TRIVALENT CHROME (INSULUBLE)(SARA 313)

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: 6.997%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

OXIDE PORTION OF CHROME OXIDE

CAS: 1317-38-9

Fraction By Weight: 1-5%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHRONIC: OVEREXPO TO SOLVENTS CAUSE
PERMANENT BRAIN/NERVOUS SYSTEM/LIVER/KIDNEY DAMAGE. OVEREXPO TO
ISOCYANATE LEADS TO RESPIRATORY SENSITIZATION CHARACTERIZED BY
ALLERGIC DERMATITIS WHICH INCLUDES RA SH, ITCHING, HIVES, SWELLING.
INGEST: IRRIT/CORROSIVE TO MOUTH/STOMAH TISSUE/DIGEST TRACT/SORE
THROAT** TRIVALENT ****
Explanation of Carcinogenicity:BASED UPON LABORATORY ANIMAL DATA, IARC
HAS LISTED SILICA AS A "PROBABLE HUMAN CARCINOGEN."
Effects of Overexposure:SKIN/EYE/RESP TRACT IRRIT (NOSE/THROAT/LUNGS).
WATERING EYES/DRY THROAT/COUGHING/HEADACHE/TIGHT CHEST/BURNING
SENSATION. SOLVENTS EXPOSURE MAY CAUSE HEADACHE/DIZZINESS/NAUSEA.
SHORTNESS OF BREATH. EXP OSURE >LIMITS MAY LEAD TO
BRONCHITIS/BRONCHIAL SPASM/PULMINARY EDEMA. CHEM/HYPERSENSITIVE
PNEUMONITIS W/FLU-LIKE SYMPTOM
Medical Cond Aggravated by Exposure:SKIN ALLERGIES AND EXEMA, ASTHMA &
OTHER RESPIRATORY AILMENTS, CHEMICAL SENSITIZATION. **** CHROME
EXPOSURE MAY CAUSE DELAYED RESP SYSTEM EFFECTS/DERMATITIS

First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. CONSULT
DR. EYES: FLUSH IMMED W/LUKE WARM RUNNING WATER 15 MINUTES, LIFTING
EYELIDS. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAM CLOTHES/WASH
BEFORE REUSE. USE SAFETY SHOWER AFTER REMOVINGCLOTHES. GET MEDICAL
AID. LESSER EXPOSURE, CONTACT DR IF IRRITATION DEVELOPS/PERSISTS.
INGESTION: CALL DR IMMED. DON'T INDUCE VOMITING.

Flash Point Method:TCC
Flash Point:54.0F,12.2C
Autoignition Temp:Autoignition Temp Text:450F
Lower Limits:0.9
Upper Limits:8.2
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, ALCOHOL FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT W/SCBA SHOULD BE
WORN. DURING A FIRE, IRRITATING & HIGHLY TOXIC GASES & SMOKE ARE
PRESENT FROM THE DECOMPOSITION/COMBUSTION PRODUCTS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO EXTREME HEAT
MAY EXPLODE OR BURST WHEN CONTAMINATED W/H20 (CO2 RELEASED). DON'T
WELD, CUT, TORCH DRUMFULL/EMPTY MAY IGNITE/EXPLODE.

Spill Release Procedures:EVACUATE NON-ESSENTIAL PERSONNEL. REMOVE IGNIT
SOURCES (FLAMES/HOT SURFACES/ELECTRICAL/STATIC/SPARKS). VENTILATE
AREA.AVOID BREATHING VAPORS. COVER W/INERT ABSORBENT.POUR
DECONTAMINANT/ALLOW TO REACT >10 MIN.COLLECT IN OPEN CNTNR/ADD
MORE DECONTAM***
Neutralizing Agent:3-8% CONCENTRAT AMMONIA/2% DETERGENT/90-95% H2O OR
TERGITOL TNN-10 20%/WATER 80%

Handling and Storage Precautions:DON'T STORE >120F OR <32F. STORE LRG
QUANTITIES IN BUILDINGS DESIGNED TO COMPLY W/OSHA 1910.106. KEEP
AWAY FROM ALL HEAT. KEEP TIGHTLY CLOSED.
Other Precautions:DON'T INGEST. GROUND WHEN POURING. AVOID POURING
LIQUID IN EXCESS OF FEW INCHES. VENTILATE, USE PROPER RESP EQUIP.
EMPTY CNTNRS RETAIN HAZARDOUS RESIDUE/EXPLOSIVE VAPORS. PROTECT
FROM MOISTURE, IF MOI STURE ENTERS PRESSURE CAN BUILD UP.

Respiratory Protection:THE SURGEON GENERAL REQUIRES AIRLINE RESPIRATORS
USED UNLESS AIR SAMPLING SHOWS EXPOSURE BELOW OSHA LIMITS. THEN
EITHER, CHEMICAL CARTRIDGE RESPIRATORS OR AIRLINE RESPIRATORS.
Ventilation:GENERAL DILUTION VENTILATION, LOCAL EXHAUST VENTILATION TO
KEEP AIR CONTAMINANT CONCENTRATION BELOW OSHA REQUIREMENTS.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:SAFETY GLASSES, FULL-FACE SHIELD
Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN
CONTACT AT A MINIMUM.
Work Hygienic Practices:REMOVE & WASH CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING & BEFORE EATING OR SMOKING.
Supplemental Safety and Health
SMOKE IN DESIGNATED AREAS ONLY. **CAUSING ABDOMINAL PAIN, NAUSEA,
VOMITING, DIARRHEA. CHRONIC OVEREXPOSURE CAN CAUSE LUNG DAMAGE.
(NOTE: MORE INFO ON FILE). ***SOLUTION. REMOVE CONTAINERS TO SAFE
PLACE, COVER LOOSELY. ALLOW TO STAND FOR 24 TO 48 HOURS. PREVENT
ENTRY INTO DRAINS/SEWERS/WATERWAYS. NOTIFY AUTHORITIES.

HCC:F2
Boiling Pt:B.P. Text:244F,118C
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Pres:15.0
Vapor Density:> AIR
Spec Gravity:1.23
Viscosity:65-68 KU
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:REACTS WITH WATER
Appearance and Odor:OPAQUE LIQUID WITH SOLVENT ODOR.

Stability Indicator/Materials to Avoid:YES
EPOXY CATALYSTS, ALCOHOLS, GLYCOL ETHERS, BASES, METAL COMPLEXES OR
OTHER ACTIVE MATERIALS.
Stability Condition to Avoid:CONTAMINATION W/H20. ONCE MATERIAL HAS
BEEN EXPOSED TO ANY OF THE BELOW OR ATMOSPHERIC MOISTURE, DON'T
SEAL CONTAINER*
Hazardous Decomposition Products:BY FIRE: CO2, CO, OXIDES OF NITROGEN,
TRACES OF HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANATE, CHLORINE.

Waste Disposal Methods:DISPOSE OF ACCORDING TO GOVERNMENT REGS.
DECONTAMINATE CONTAINERS BEFORE DISPOSAL.

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document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.